@prefix config: . @prefix meta: . @prefix rdf: . @prefix rdfs: . @prefix xsd: . @prefix owl: . @prefix dc: . @prefix dcmitype: . @prefix dcterms: . @prefix foaf: . @prefix geo: . @prefix om: . @prefix locn: . @prefix schema: . @prefix skos: . @prefix dbpedia: . @prefix p: . @prefix yago: . @prefix units: . @prefix geonames: . @prefix prv: . @prefix prvTypes: . @prefix doap: . @prefix void: . @prefix ir: . @prefix ou: . @prefix teach: . @prefix time: . @prefix datex: . @prefix aiiso: . @prefix vivo: . @prefix bibo: . @prefix fabio: . @prefix vcard: . @prefix swrcfe: . @prefix frapo: . @prefix org: . @prefix ei2a: . @prefix pto: . bibo:eissn "1521-3765"; ou:vecesCitado "8"; ou:urlOrcid ; ou:eid "2-s2.0-85031725204"; bibo:page_range "17870-17873"; dcterms:contributor "Fombona S., Perez J., Diaz J., Riera L."; dcterms:title "Intermolecular C−C Coupling between 1-Methyl-1,2,3-Triazole and 2,2′-Bipyridine or 1,10-Phenanthroline in MoII Complexes"; bibo:issn "0947-6539"; ou:bibtex "@article{doi:10.1002/chem.201703524, author= {Fombona Sergio and Pérez Julio and Díaz Jesús and Riera Lucía}, title= {Intermolecular C−C Coupling between 1-Methyl-1,2,3-Triazole and 2,2′-Bipyridine or 1,10-Phenanthroline in MoII Complexes}, journal= {Chemistry – A European Journal}, volume= {23}, number= {71}, pages= {17870-17873}, keywords= {carbonyl complexes, C−C coupling, dearomatization, molybdenum, triazole}, doi= {10.1002/chem.201703524}, url= {https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201703524}, eprint= {https://onlinelibrary.wiley.com/doi/pdf/10.1002/chem.201703524}, abstract= {Abstract Unsupported 1-methyl-1,2,3-triazole has been coordinated to {Mo(η3-methallyl)(CO)2(N-N)} (N-N=2,2′-bipyridine, bipy; or 1,10-phenanthroline, phen) fragments, yielding cationic complexes that can be regarded as metalated triazolium salts. Their reactivity towards a strong base led to the deprotonation of the C5−H group of the triazole moiety, followed by an intermolecular nucleophilic attack to the ortho CH group of a bipy or phen ligand affording cyclic, bimetallic dearomatized C−C coupling products. The reaction of the neutral bipy derivative with an acid led to the formation of dihydropyridyl units by protonation of a CH group of the dearomatized rings, the dimeric nature of complexes being mantained upon protonation.}}"; fabio:hasPublicationYear "2017"; vivo:identifier "2017-562"; bibo:doi "10.1002/chem.201703524"; ou:urlScopus ; vcard:url ; dcterms:publisher "Chemistry - A European Journal"; ou:tipoPublicacion "Article"; a ou:Publicacion; bibo:volume "23"; dcterms:creator "Fombona S."; ou:publicadaEnRevista . ou:tienePublicacion .